Functions of insulating oil in transformers:
1. Insulation: Transformer oil has much higher insulation strength than air. The insulating material is immersed in oil, which not only improves the insulation strength, but also protects it from moisture.
2. Heat dissipation: Transformer oil has a large specific heat and is often used as a coolant.
3. Arc extinguishing effect: Because the transformer oil has good thermal conductivity, and can decompose a large amount of gas under the high temperature of the arc, it can generate a large pressure, thereby improving the arc extinguishing performance of the medium and quickly extinguishing the arc.
Density
or relative density is related to the composition of oil and the amount of
water present. For transformer oil, controlling its density also controls the
amount of water in the oil in a sense, especially for preventing transformers
working in cold areas from appearing ice floes during temporary outages in
winter. If there is too much water in the transformer oil, ice crystals will
adhere to the electrode when the temperature is low, but when the temperature
rises, the ice crystals adhered to the electrode will melt, increase
conductivity, and cause the danger of discharge. The density of this pair of
insulating oils is generally required to be no more than 895kg/㎡ at 20°C.
In the
transformer, transformer oil is used as a medium for insulating and
transferring heat. It is required to select a suitable viscosity to ensure that
the oil has an ideal cooling effect in long-term operation, and a reasonable
low-temperature viscosity to ensure that the transformer can work safely when
it is stopped and restarted. . Therefore, the United States ASTM 19487
transformer oil standard specifies the requirements of 0°C and 100°C kinematic
viscosity, and the IEC 296 standard promulgated by the International
Electrotechnical Commission also specifies 40°C, -15°C (or -30°C, -40°C)
kinematic viscosity Requirements. Excessive viscosity affects heat transfer,
and vice versa reduces work safety.
The
freezing point of transformer oil is the highest temperature at which the oil
level does not move. The pour point is the lowest temperature at which
transformer oil can flow. Transformer oil is a mixture of different
hydrocarbons, and the freezing points of various hydrocarbons are also
different. Therefore, when the temperature drops, it does not solidify
immediately. It has to go through a thickening stage and gradually solidify in
a wide temperature range. Therefore, the freezing point or pour point is only
the approximate maximum temperature when the transformer oil loses fluidity.
The freezing point and pour point reflect the low temperature of the oil to a
certain extent. In the GB-7595 in-service transformer oil quality standard
promulgated by China, it is stipulated that when additional switch oil is added
with a pour point depressant, the freezing point test should be added and the
temperature should be specified. In areas below -5°C, the freezing point of oil
products is not higher than -10°C; in areas where the temperature is lower than
-10°C, the freezing point of oil products is not higher than -25°C; in areas
where the temperature is lower than -25°C, oil products The freezing point is
not higher than -45°C. If it is used in a climate below the freezing point, the
oil will lose its flow and the equipment will not be able to start and work.
Flash
point is an important safety indicator during storage and use of transformer
oil, especially for monitoring transformer oil in operation. Flash point is an
indispensable item. The decrease in flash point indicates that there are
volatile combustibles in the oil. These low-molecular hydrocarbons are often
produced when the insulating oil is thermally cracked at high temperatures due
to overheating caused by partial failure of electrical equipment. Therefore,
electrical equipment can be discovered in time through flash point monitoring.
Whether there is an overheating fault, for the newly charged equipment and the
transformer oil after maintenance, measuring the flash point can find out
whether there is light distillate oil mixed in. If the flash point is too low,
it will cause a fire or even an explosion in electrical equipment. Therefore,
there are strict flash point control indicators in the new oil standards for
transformer oils in various countries. Generally, the closed flash point is not
less than 140°C, and the open flash point is not less than 145°C. The flash
point of "operating oil" is also strictly controlled, and the flash
point drop value measured each time shall not be 5°C lower than the previous
time.
The acid
value indicates that the oil contains acidic substances, that is, the total
value of organic acids and inorganic acids. Generally, the acid is expressed in
mg of potassium hydroxide required to neutralize the acidic substances in 1g of
transformer oil. For new transformer oil that has not been used Almost no
acidic substances, its acid value is quite small, but oil products will
inevitably come into contact with oxygen in the air after long-term storage,
especially after the electrical equipment is charged into operation, and the
oil products are easy to be aged, and the production is mainly low in the
initial stage of oxidation. Molecular organic acids are further oxidized to
produce polymer organic acids and acid products. The presence of the
above-mentioned acidic substances in the excellent product will increase the
conductivity of the oil, reduce the insulation performance of the oil, and may
also cause corrosion to metals. . In the case of high operating temperature
(above 80°C), the solid fiber paper insulation material is promoted to aging,
thereby shortening the service life of the equipment.
The acid
value of the unused transformer oil is generally 0.01mgKOH/g, and the acid
value of the operating oil is controlled not to exceed 0.1mgKOH/g.
Generally,
the unused (new) transformer oil contains almost no acidic substances, and its
acid value is low, with a pH value in the range of 6-7. The pH value is mainly
used to indicate the index of the water-soluble acid of the insulating oil.
According to the oil analysis of China's on-site investigations, simulation
tests and laboratory aging test results, the transformer oil generally has an
acid value greater than 0.1mgKOH/g and the pH value is equal to or less than
4.0 when the transformer operating oil is more likely to precipitate sludge. On
the contrary, the transformer oil can basically ensure the good and reliable
operation of the transformer. When the acid value rises above 0.2mgKOH/g or the
pH value is lower than 3.8, the oil quality deteriorates significantly and more
sludge is produced. Therefore, the pH value of the operating oil should be
greater than 4.2.
Breakdown
voltage is an index for evaluating the electrical performance of transformer
oil. It can be used to determine the degree of water and other suspended solids
pollution in the oil, as well as the inspection of the degree of drying and
filtration of the oil before it is injected into the equipment. When a
gradually increasing voltage is applied to the clean and dry oil, shooting
electrons will be emitted at the negative end of the voltage. When the
electrons have sufficient energy, the oil molecules can be micro-dissociated.
Therefore, the entire dissociation process is strengthened as the voltage
rises. When a certain voltage is reached, a large amount of conduction current
will be generated to form an arc. This phenomenon is called breakdown, and the
voltage during breakdown is called breakdown voltage. If there is water or
solids in the oil, the breakdown voltage will be reduced. At this time, the
conductivity of water and solids is greater than that of oil. The low breakdown
voltage of the oil during operation is a signal of the dangerous work of the
transformer. For transformer oil, the breakdown voltage specified in the
domestic and foreign standards is generally 40-50kV, with a high of 60kV or
even more.
Permittivity
is also called permittivity (or relative permittivity), which measures the
ratio of the capacitance between and around the two electrodes of a capacitor
when only insulating oil is filled with the vacuum capacitance of the same
plate. Different oil products have different permittivities. The permittivity
usually changes with temperature and frequency. In actual use, the oil's
permittivity changes with temperature and frequency as small as possible.
The
dielectric loss factor of the insulating oil is expressed by the tangent of the
dielectric loss angle, and the dielectric loss angle is the phase angle and
complementary angle between the applied AC voltage and the current passing
through it.
Transformer
oil exists as an insulating medium in transformers or similar equipment. Under
the action of the changing electric field generated by the AC circuit,
theoretically only a weak capacitive current can pass through the medium. The
phase between it and the applied voltage is 90°C earlier, so it is a reactive
current, which only affects the power factor of the device and does not cause
power loss, but in fact there will be more or less in the oil that can make the
internal charge imbalance or due to electric field The polar molecules produced
by the action, they can act as conductors, thereby generating resistive
conduction current (or leakage current). This current is in phase with the
applied voltage, so it is an active current that causes power loss, which is
called dielectric loss of insulating oil, which is expressed by the ratio of
conduction current to capacitive current (delay), which is called dielectric
loss factor. Dielectric loss factor is an important index to evaluate the
electrical performance of transformer oil, especially the deterioration or
contamination of oil will cause more obvious changes in the loss factor of the
medium. There are few polar substances in new oil, so the dielectric loss
factor is generally in the range of 0.0001 to 0.001. If the operating oil loss
factor is too large, measures must be taken.
(1).
Interfacial tension means the tension between insulating oil and immiscible
water;
(2).
Oxidation products, sludge, etc. produced by oil products due to aging and
deterioration after use have an impact on the interfacial tension. (3) The
interfacial tension of unused transformer oil can generally reach 40-50mN/m.
After the oil is aged, various organic acids (one COOH) and alcohol (one OH)
and other polar substances are generated, which makes the oil The interfacial
tension gradually decreases.
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